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The velocity of such a ping-pong reaction with infinite true k cat and K m values can be described by the equation [ E ]/ V =Φ 1 /[GSSCys]+Φ 2 /[GSH], wherein the Dalziel coefficients Φ 1 and Φ 2 are the slopes of secondary plots for k cat app (GSH) and k cat app (GSSCys) , respectively 39 (Supplementary Table 1)